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R1: saturated fatty acid + CoA-SH + ATP ⟹ saturated fatty acyl-CoA + AMP + diphosphatediphosphateAMPsaturated fatty acyl-CoACoA-SHATPsaturated fatty acidLcfBLcfAR2: saturated fatty acyl-CoA + FAD ⟹ trans-2-onyl-CoA + FADH2FADH2trans-2-onyl-CoAFADsaturated fatty acyl-CoAAcdAFadER6: Fatty acyl N-2 CoA ⟹ saturated fatty acyl-CoAsaturated fatty acyl-CoAFatty acyl N-2 CoAR5: 3-oxoacyl-CoA ⟹ Fatty acyl N-2 CoA + acetyl-CoAacetyl-CoAFatty acyl N-2 CoA3-oxoacyl-CoAFadAR4: 3-hydroxyacyl-CoA + NAD+ ⟹ 3-oxoacyl-CoA + NADH + H+NADHH+3-oxoacyl-CoANAD+3-hydroxyacyl-CoAR3: trans-2-onyl-CoA + H2O ⟹ 3-hydroxyacyl-CoA3-hydroxyacyl-CoAH2Otrans-2-onyl-CoAFadBR13: FADH2 + ETFH2 ⟹ ETF + FADFADETFFADH2ETFH2EtfA;EtfBEtfAEtfBR8: unsaturated fatty acid-CoA + NADH + H+ ⟹ trans-2-onyl-CoA + NAD+NAD+trans-2-onyl-CoANADHH+unsaturated fatty acid-CoAFadHR9: 3-hydroxyacyl-ACP ⟹ enoyl-acyl ACP + H2OH2Oenoyl-acyl ACP3-hydroxyacyl-ACPYcsDYwpBR21: ß-ketoacyl-ACP + NADPH + H+ ⟹ 3-hydroxyacyl-ACP + NADP+NADP+3-hydroxyacyl-ACPNADPHH+ß-ketoacyl-ACPFabGR20: acetoacetyl-ACP ⟹ ß-ketoacyl-ACPß-ketoacyl-ACPacetoacetyl-ACPR10: enoyl-acyl ACP + NADH + H+ ⟹ saturated fatty acyl N-2 ACP + NAD+NAD+saturated fatty acyl N-2 ACPNADHH+enoyl-acyl ACPFabIR14: saturated fatty acyl N-2 ACP ⟹ acetoacetyl-ACPacetoacetyl-ACPsaturated fatty acyl N-2 ACPR19: acetyl-CoA + malonyl-ACP ⟹ acetoacetyl-ACP + ACP SH + CO2CO2acetoacetyl-ACPACP SHacetyl-CoAmalonyl-ACPFabFR16: acetyl-ACP + malonyl-ACP ⟹ acetoacetyl-ACP + ACP SH + CO2CO2acetoacetyl-ACPACP SHmalonyl-ACPacetyl-ACPFabHAFabFFabHBR18: malonyl-CoA + AcpA ⟹ malonyl-ACP + CoA-SHCoA-SHmalonyl-ACPmalonyl-CoAAcpAFabDR17: acetyl-CoA + ATP + HCO3 ⟹ malonyl-CoA + ADP + phosphatephosphateADPmalonyl-CoAacetyl-CoAATPHCO3AccCAccAAccBAccD

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